X-ray Spectromicroscopy of Mineral Intergrowths in the Santa Catharina Meteorite     

Paul F. Schofield  Andrew D. Smith  J. Frederick W. Mosselmans  Hendrik Ohldag  Andreas Scholl  Simone Raoux  Gordon Cressey  Barbara A. Cressey  Paul D. Quinn  Caroline A. Kirk  Simon C. Hogg 《Geostandards and Geoanalytical Research》2010,34(2):145-159

This work describes the application of microfocus X-ray absorption spectroscopy (XAS) and X-ray photo-emission electron microscopy (XPEEM) to the study of the complex mineralogical intergrowths within the Santa Catharina meteorite. The Santa Catharina meteorite of this study (BM52283 from the meteorite collection of the Natural History Museum, London, UK) primarily comprises a taenite bulk host phase (Fe:Ni ratio = 70.9 ± 0.8%:29.1 ± 0.8%) with a set of oxide-bearing cloudy zone textured regions (Fe:Ni:O ratio = 40.4 ± 0.3%:49.0 ± 0.7%:10.6 ± 0.8% at the core and Fe:Ni:O ratio = 34.4 ± 1.5%:42.7 ± 0.6%:22.9 ± 1.8% towards the rims) and numerous schreibersite (Fe:Ni:P ratio = 38.6 ± 1.6%:38.4 ± 0.9%:23.0 ± 0.5%) inclusions. Between the schreibersite and the taenite are rims up to 50 μm across of Ni-rich kamacite (Fe:Ni ratio = 93.4 ± 0.4%:6.6 ± 0.5%). No chemical zoning or spatial variations in the Fe and Ni speciation was observed within either the schreibersite or the kamacite phases. The oxide-bearing cloudy zone textured regions mostly comprise metallic Fe–Ni alloy, predominantly tetrataenite. Within the oxide phases, the Fe is predominantly, but not entirely, tetrahedrally co-ordinated Fe³⁺ and the Ni is octahedrally co-ordinated Ni²⁺. Structural analysis supports the suggestion that non-stoichiometric Fe₂NiO₄ trevorite is the oxide phase. The trevorite:tetrataenite ratio increases at the edges of the oxide-bearing cloudy zone textured regions indicating increased oxidation at the edges of these zones. The spatial resolution of the XPEEM achieved was between 110 and 150 nm, which precluded the study of either the previously reported ∼ 10 nm precipitates of tetrataenite within the bulk taenite or any antitaenite.  相似文献   

Growth dynamics and bioactivity variation of the Mediterranean demosponges Agelas oroides (Agelasida, Agelasidae) and Petrosia ficiformis (Haplosclerida, Petrosiidae)     

Cristina Ferretti  Simone Vacca  Chiara De Ciucis  Barbara Marengo  Alan R. Duckworth  Renata Manconi  Roberto Pronzato  & Cinzia Domenicotti 《Marine Ecology》2009,30(3):327-336

Growth dynamics and bioactivity variation of the Mediterranean demosponges Agelas oroides and Petrosia ficiformis were investigated over 15 months at Paraggi and Colombara within the Marine Reserve of Portofino Promontory (Mediterranean Sea, Ligurian Sea, Italy). For both species, growth rates varied between individuals and were unaffected by initial sponge size. The two species showed a different trend in growth pattern: A. oroides did not vary significantly between seasons, sites and depths; in contrast, some individuals of P. ficiformis showed a seasonal pattern, shrinking during winter as water temperature decreased and growing during summer when water temperature increased. Differences in growth between the two species may result from different reproductive cycles, food availability, species-specific thermophily and patterns of spatial competition. Moreover, spatial competition probably induced sponges to produce bioactive secondary molecules. Spatial and temporal variation of bioactivity of both species was examined for the first time by studying its effect on human neuroblastoma cells. The bioactivity of A. oroides extracts differed significantly between seasons, sites and depths, whereas the cytotoxicity of P. ficiformis differed significantly between seasons and depths (differences for sites were not determined). These results suggest the possible influence of environmental factors on bioactive metabolite biosynthesis.  相似文献   

The phase-space parameters of the brightest halo galaxies     

Frank C. van den Bosch  Simone M. Weinmann  Xiaohu Yang  H. J. Mo  Cheng Li  Y. P. Jing 《Monthly notices of the Royal Astronomical Society》2005,361(4):1203-1215

  相似文献   

Modulation of Galactic Protons in the Heliosphere During the Unusual Solar Minimum of 2006 to 2009     

M. S. Potgieter  E. E. Vos  M. Boezio  N. De Simone  V. Di Felice  V. Formato 《Solar physics》2014,289(1):391-406

The last solar minimum activity period, and the consequent minimum modulation conditions for cosmic rays, was unusual. The highest levels of galactic protons were recorded at Earth in late 2009 in contrast to expectations. Proton spectra observed for 2006 to 2009 from the PAMELA cosmic ray detector on-board the Resurs-DK1 satellite are presented together with the solutions of a comprehensive numerical model for the solar modulation of cosmic rays. The model is used to determine what mechanisms were mainly responsible for the modulation of protons during this period, and why the observed spectrum for 2009 was the highest ever recorded. From mid-2006 until December 2009 we find that the spectra became significantly softer because increasingly more low energy protons had reached Earth. To simulate this effect, the rigidity dependence of the diffusion coefficients had to decrease significantly below ～?3 GeV. The modulation minimum period of 2009 can thus be described as relatively more ‘diffusion dominated’ than previous solar minima. However, we illustrate that drifts still had played a significant role but that the observable modulation effects were not as well correlated with the waviness of the heliospheric current sheet as before. Protons still experienced global gradient and curvature drifts as the heliospheric magnetic field had decreased significantly until the end of 2009, in contrast to the moderate decreases observed during previous minimum periods. We conclude that all modulation processes contributed to the observed increases in the proton spectra for this period, exhibiting an intriguing interplay of these major mechanisms.  相似文献   

Adaptive optics at short wavelengths     

Guido Agapito  Carmelo Arcidiacono  F. Quirós-Pacheco  Simone Esposito 《Experimental Astronomy》2014,37(3):503-523

The First Light Adaptive Optics (FLAO) system has been successfully commissioned at the Large Binocular Telescope. It delivers extreme adaptive optics performance using bright natural guide stars reaching 90 % Strehl Ratios in H-band. Observations with current adaptive optics systems are limited to the near infrared wavelengths, in these bands the diffraction limited resolution of the largest ground-based telescopes (8–10 meter class) is comparable to the one of the much smaller Hubble Space Telescope that observes in the visible bands. This study aims to demonstrate the feasibility of an adaptive optics system designed to achieve very high order correction at visible wavelengths (0.5 to 0.8 μ m) with significant sky coverage. Upgrading the FLAO design with a low noise CCD relaxes the reference magnitude limit needed to achieve greater performance. In particular, we demonstrate that a gain of 1–2 magnitudes is possible by upgrading the wavefront sensor with a very low read out noise CCD. For future AO systems, in addition to low noise CCDs, deformable (secondary) mirrors with a higher actuator density will be able to move the high order correction capability from the near infrared to the visible wavelengths (Strehl Ratio of 80 % in R (0.7 μ m), 60 % in V (0.5 μ m)). We investigate, by means of numerical simulation, the gain in imaging performance obtained at Near Infrared, Visible, and UV wavelengths. The results of these simulations have been used to derive the empirical relation between Strehl Ratio and magnitude of the reference star and we then use this relationship to perform a detailed sky coverage analysis based on astronomical catalog data. The detailed simulations of the Point Spread Functions allow us to compute Ensquared Energy and Strehl Ratio for the magnitude working range of such an Adaptive Optics system. We present the results of the instrumental isoplanatic angle determination. We then used these values to compute the relationship between correction level and the off-axis angle from the reference star. The Strehl Ratio relationship with the reference magnitude and the angular distance provides the information needed to perform the sky-coverage analysis, which demonstrates that the designed system is able to provide V and R bands correction on a not negligible few percent of the sky.  相似文献   

High Resolution Simulation of the Variability of Surface Energy Balance Fluxes Across Central London with Urban Zones for Energy Partitioning     

Thomas Loridan  Fredrik Lindberg  Oriol Jorba  Simone Kotthaus  Susanne Grossman-Clarke  C. S. B. Grimmond 《Boundary-Layer Meteorology》2013,147(3):493-523

The parameterization of surface heat-flux variability in urban areas relies on adequate representation of surface characteristics. Given the horizontal resolutions (e.g. $\approx $ 0.1–1 km) currently used in numerical weather prediction (NWP) models, properties of the urban surface (e.g. vegetated/built surfaces, street-canyon geometries) often have large spatial variability. Here, a new approach based on Urban Zones to characterize Energy partitioning (UZE) is tested within a NWP model (Weather Research and Forecasting model; WRF v3.2.1) for Greater London. The urban land-surface scheme is the Noah/Single-Layer Urban Canopy Model (SLUCM). Detailed surface information (horizontal resolution 1 km) in central London shows that the UZE offers better characterization of surface properties and their variability compared to default WRF-SLUCM input parameters. In situ observations of the surface energy fluxes and near-surface meteorological variables are used to select the radiation and turbulence parameterization schemes and to evaluate the land-surface scheme and choice of surface parameters. For radiative fluxes, improved performance (e.g. $>$ 25 W m $^{-2}$ root-mean-square error reduction for the net radiation) is attained with UZE parameters compared to the WRF v3.2.1 default for all three methods from the simplest to the most detailed. The UZE-based spatial fluxes reproduce a priori expectations of greater energy storage and less evaporation in the dense city centre compared to the residential surroundings. Problems in Noah/SLUCM partitioning of energy between the daytime turbulent fluxes are identified with the overestimation of the turbulent sensible heat and underestimation of the turbulent latent heat fluxes.  相似文献   

Properties of galaxy groups in the Sloan Digital Sky Survey – I. The dependence of colour, star formation and morphology on halo mass     

Simone M. Weinmann  Frank C. van den Bosch  Xiaohu Yang  H. J. Mo 《Monthly notices of the Royal Astronomical Society》2006,366(1):2-28

  相似文献   

The stellar velocity distribution in the solar neighbourhood     

Richard S. De Simone  Xiaoan Wu †  Scott Tremaine 《Monthly notices of the Royal Astronomical Society》2004,350(2):627-643

  相似文献   

The ineligible majority: Urbanizing the postcolony in Africa and Southeast Asia     

AbdouMaliq Simone 《Geoforum》2011,42(3):266-270

  相似文献   

Are metal-induced hypersensitivities in harbor seals associated with liver function?     

Kakuschke A  Valentine-Thon E  Griesel S  Fonfara S  Siebert U  Prange A 《Marine pollution bulletin》2011,62(8):1891-1894

Environmental exposure to metals is believed to affect marine mammal health adversely including immunosuppression or acute as well as chronic inflammatory processes leading to hypersensitivities or autoimmune diseases. Metal-specific hypersensitivities were found in several pinnipeds of the North Sea. However, hypersensitivity is a complex phenomenon whose characteristics are still not completely understood; in particular, effects on health are not well established. In the present study, we compared basic hematological and biochemical parameters of seals with and without metal-specific hypersensitivities. We found altered hematological parameters and liver enzyme patterns in seals with a metal-induced hypersensitivity, including a reduction in macrophages, an increase in lymphocytes, and elevated levels of lactate dehydrogenase. These findings support the suggestion of a chronic influence of metal pollutants on the health of marine mammals of the North Sea.  相似文献